Exception Type: EXC_CRASH (Code Signature Invalid)
Exception Codes: 0x0000000000000000, 0x0000000000000000
Exception Note: EXC_CORPSE_NOTIFY
Termination Reason: Namespace CODESIGNING, Code 0x1
To my inexpert eye, that looks like your culprit, but I can't begin to guess why it's reared its ugly head out of the blue.
I suspect that PrintLife's developer will be best able to figure out what's going on. (Are all the crash reports the same?)